化工社化工社 化学情報印刷レポート · 研究参考用
Water → Phenacyltetrahydrothiophenium bromide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Tetrahydrothiophene | HCID 1127 | — |
| 反応物 | Diethyl Ether | HCID 3283 | — |
| 反応物 | Phenacyl bromide | HCID 6259 | — |
| 溶媒 | Nitromethane | HCID 6375 | — |
| 生成物 | Phenacyltetrahydrothiophenium bromide | HCID 11346720 | — |
反応手順
88.2 g (0.44 mole) of phenacyl bromide and 39.1 g (0.44 mole) of tetrahydrothiophene were dissolved in 220 g of nitromethane, which was stirred for 4 hours at room temperature. 800 g of water and 400 g of diethyl ether were added to the reaction solution whereupon the mixture separated into two layers. The aqueous layer was taken out, which was an aqueous solution of the target compound, phenacyltetrahydrothiophenium bromide.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07556909B2 |
| 出典データセット | uspto-grants-2009_07 |
| ORD ID | ord-e340a01c97f3477caf8d844c91753b25 |
| 出典メモ | uspto-grants-2009_07 |