Dimethylamine → 5-Nitro-6-dimethylaminoquinoline
反応式
[N+:1]([C:4]1[C:13](Cl)=[CH:12][CH:11]=[C:10]2[C:5]=1[CH:6]=[CH:7][CH:8]=[N:9]2)([O-:3])=[O:2].[CH3:15][NH:16][CH3:17]>>[N+:1]([C:4]1[C:13]([N:16]([CH3:17])[CH3:15])=[CH:12][CH:11]=[C:10]2[C:5]=1[CH:6]=[CH:7][CH:8]=[N:9]2)([O-:3])=[O:2]参加物
3
実験手順
5-Nitro-6-chloroquinoline, prepared as described by Manske & Kulka, Organic Reactions, Vol. VII, 59 (1953) and Campbell et al., J. Am. Chem. Soc., 68, 1559 (1946), was allowed to react with dimethylamine to yield 5-nitro-6-dimethylaminoquinoline. This material was converted to the title compound by the procedure described in Example 33.
出典と根拠
- ORDレコード
- ord-aaeee53c8bd74854b4c49490fa0f8acd
- 出典データセット
- uspto-grants-1997_08
- 特許番号
- US05656634
反応ノート
読み込み中…