化工社化工社 化学情報印刷レポート · 研究参考用
Diethylaluminum chloride → 1-Octene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Diethylaluminum chloride | HCID 7277 | — |
| 反応物 | Heptane | HCID 8900 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 生成物 | 1-Octene | HCID 8125 | — |
| 生成物 | 1,7-Octadiene | HCID 19460 | — |
反応手順
A solution of 81.5 grams (0.966 mole) 1-octene and 5.61 grams (0.0509 mole) 1,7-octadiene (molar charge ratio 95:5) in 450 grams of heptane was polymerized with Et2AlCl (16 millimoles) and AATiCl3 (4 millimoles) at 50° C. for 10 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 52 percent, inherent viscosity was 1.9 dl/gram. The composition of monomers in the copolymer was 97:3 mole ratio from NMR analysis.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05428209 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-87da2cd7a1004668b0b227c1ea33b62b |
| 出典メモ | uspto-grants-1995_06 |