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Diethylaluminum chloride → 1-Hexene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Diethylaluminum chloride | HCID 7277 | — |
| 反応物 | Heptane | HCID 8900 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 生成物 | 1-Hexene | HCID 11597 | — |
| 生成物 | 1,7-Octadiene | HCID 19460 | — |
反応手順
A solution of 985.94 grams (11.715 mole) 1-hexene and 58.24 grams (0.4831 mole) 1,7-octadiene (molar charge ratio 96:4) in 450 grams of heptane was polymerized with Et2AlCl (13.5 millimoles) and AATiCl3 (6.97 millimoles) at 25° C. for 20 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 62 percent, inherent viscosity was 1.6 dl/gram. The composition of monomers in the copolymer was 97.8:2.2 mole ratio from NMR analysis.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05428209 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-c9abef9a5c4546839e88ada6111053af |
| 出典メモ | uspto-grants-1995_06 |