化工社化工社 化学情報印刷レポート · 研究参考用
Diethylaluminum chloride → 1-Octene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Diethylaluminum chloride | HCID 7277 | — |
| 反応物 | Heptane | HCID 8900 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 生成物 | 1-Octene | HCID 8125 | — |
| 生成物 | 1,7-Octadiene | HCID 19460 | — |
反応手順
A solution of 416.53 grams (3.711 mole) 1-octene and 8.35 grams (0.0758 mole) 1,7-octadiene (molar charge ratio 98:2) in 450 grams of heptane was polymerized with Et2AlCl (4.14 millimoles) and AATiCl3 (2.75 millimoles) at 25° C. for 26 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 56 percent, inherent viscosity was 1.3 dl/g. The composition of monomers in the copolymer was 99:1 mole ratio from NMR analysis.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05428209 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-cfe8c2df7237419abf87a52f7ed77414 |
| 出典メモ | uspto-grants-1995_06 |