6-Methoxy-2-(1-cyclohexenyl)benzo[b]thiophene → 6-Methoxy-2-cyclohexylbenzo[b]thiophene
反応式
[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[CH:10]=[C:9]([C:11]3[CH2:16][CH2:15][CH2:14][CH2:13][CH:12]=3)[S:8][C:7]=2[CH:17]=1>C(OCC)(=O)C.[C].[Pd]>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[CH:10]=[C:9]([CH:11]3[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12]3)[S:8][C:7]=2[CH:17]=1参加物
4
実験手順
5 g of 6-methoxy-2-(1-cyclohexenyl)benzo[b]thiophene was dissolved in 20 ml of ethyl acetate, 800 mg of 5% palladium-carbon was added, and hydrogenation was carried out at room temperature and at atmospheric pressure. The reaction mixture was filtered, and the filtrate was concentrated to obtain 2.5 g of 6-methoxy-2-cyclohexylbenzo[b]thiophene.
後処理
- customwas carried out at room temperature and at atmospheric pressure
- filtrationThe reaction mixture was filtered
- concentrationthe filtrate was concentrated
出典と根拠
- ORDレコード
- ord-5e1e3040b23446efa25e8ed91ab7e706
- 出典データセット
- uspto-grants-1995_12
- 特許番号
- US05472962
反応ノート
読み込み中…