Cyclohexyl formate → Cyclohexanol

HRID 2260036ノート

反応式

HRID 2260036 の反応式
[CH:1]([O:3][CH:4]1[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5]1)=[O:2]>O>[CH:1]([O:3][CH:4]1[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5]1)=[O:2].[CH:4]1([OH:3])[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5]1

参加物

5

反応物 2

HCID 20358Cyclohexyl formateHCID 178506046HCID 178506046、化合物

生成物 2

HCID 7966CyclohexanolHCID 20358Cyclohexyl formate

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
110 °C

実験手順

Using a procedure analogous to that employed in Example 1, 1.28 g of cyclohexyl formate, 1.8 g of water, and 0.5 g of a sulfonated polytetrafluoroethylene were heated at 110° C. over a period of 2 h. Following separation of the catalyst and homogenization with acetone there were obtained, in addition to unconverted cyclohexyl formate, 70.2 mol % of cyclohexanol, and the only by-product was 1.8 mol % of cyclohexene.

後処理

  1. customseparation of the catalyst and homogenization with acetone

出典と根拠

ORDレコード
ord-31231c9307f342118c2a247229c11b9e
出典データセット
uspto-grants-1995_12
特許番号
US05475158

反応ノート

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