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Chlorotrimethylsilane → N,N-bis(trimethylsilyl)perfluorooctaneamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Chlorotrimethylsilane | HCID 6397 | — |
| 反応物 | Hexadecane | HCID 11006 | — |
| 反応物 | 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctanamide | HCID 67919 | — |
| 溶媒 | Hexane | HCID 8058 | — |
| 生成物 | N,N-bis(trimethylsilyl)perfluorooctaneamide | HCID 86615112 | — |
反応手順
First, perfluorooctaneamide (CF3(CF2)7CONH2) (46 g) was dissolved in n-hexane (300 ml). Thereafter, trimethylchlorosilane (15 ml) was dropped gradually into the solution obtained above, in a dry nitrogen atmosphere. Then this was allowed to react for two hours while being stirred. After the reaction was completed, hexadecane contained in the reaction solution was removed with the evaporator. Thus, N,N-bis(trimethylsilyl)perfluorooctaneamide was obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07560301B2 |
| 出典データセット | uspto-grants-2009_07 |
| ORD ID | ord-297020bd8b424536ad1a50bc562a8510 |
| 出典メモ | uspto-grants-2009_07 |