Methyl 4-(methylamino)-3-nitrobenzoate → HCID 118158960、化合物
反応式
[CH:1]1([CH2:4][N:5]2[C:9]3=[N:10][CH:11]=[CH:12][CH:13]=[C:8]3[CH:7]=[C:6]2[C:14]2[N:18]([CH3:19])[C:17]3[C:20](OC)=[CH:21][C:22]([C:24]([O:26][CH3:27])=[O:25])=[CH:23][C:16]=3[N:15]=2)[CH2:3][CH2:2]1.CNC1C=CC(C(OC)=O)=CC=1[N+]([O-])=O.C1(CN2C3=NC=CC=C3C=C2C=O)CC1>>[CH:1]1([CH2:4][N:5]2[C:9]3=[N:10][CH:11]=[CH:12][CH:13]=[C:8]3[CH:7]=[C:6]2[C:14]2[N:18]([CH3:19])[C:17]3[CH:20]=[CH:21][C:22]([C:24]([O:26][CH3:27])=[O:25])=[CH:23][C:16]=3[N:15]=2)[CH2:3][CH2:2]1参加物
4
実験手順
Prepared in a similar manner to Intermediate 44 using methyl 4-(methylamino)-3-nitrobenzoate (89 mg, 0.424 mmol) and 1-(cyclopropylmethyl)-1H-pyrrolo[2,3-b]pyridine-2-carbaldehyde (85 mg, 0.424 mmol).