HCID 86702659、化合物 → HCID 86702658、化合物
反応式
[C:1]1(/[CH:7]=[CH:8]/[CH2:9][CH2:10][CH2:11][C:12]#[C:13][C:14](=[O:16])[CH3:15])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1>ClCCCl>[CH2:9]1[C:8]2=[CH:7][C:1]3[C:6]([C:13]([C:14](=[O:16])[CH3:15])=[C:12]2[CH2:11][CH2:10]1)=[CH:5][CH:4]=[CH:3][CH:2]=3参加物
3
反応条件
- 温度
- 180 °C
実験手順
To a 0.5-2 mL microwave irradiation vial equipped with a stir bar was added enyne 5a (0.020 g, 0.094 mmol) in DCE (1.6 mL). The reaction was irradiated with stirring at 180° C. for 30 min until complete by TLC. The reaction turned golden in color. The reaction was then transferred to a vial, concentrated under reduced pressure, and dried under vacuum to yield naphthalene 6a as a black oil (0.020 g, quant.).
後処理
- customTo a 0.5-2 mL microwave irradiation
- customvial equipped with a stir bar
- customThe reaction was irradiated
- concentrationconcentrated under reduced pressure
- customdried under vacuum
出典と根拠
- ORDレコード
- ord-15ba7f22b0104297afa6bd7ae1bc2360
- 出典データセット
- uspto-grants-2015_09
- 特許番号
- US09133234B2
反応ノート
読み込み中…