Methoxydiphenylphosphine → HCID 54544134、化合物

反応式

[CH3:1][C:2]([CH2:10][CH3:11])([CH2:6][CH2:7][CH2:8][CH3:9])[C:3](Cl)=[O:4].C[O:13][P:14]([C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>>[CH3:1][C:2]([CH2:10][CH3:11])([CH2:6][CH2:7][CH2:8][CH3:9])[C:3]([P:14](=[O:13])([C:21]1[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=1)[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)=[O:4]

参加物

反応物 2

HCID 77636Methoxydiphenylphosphine

HCID 227590852-Ethyl-2-methylhexanoyl chloride

生成物 1

HCID 54544134HCID 54544134、化合物

実験手順

Using a method similar to that of Example 1, 88 parts of 2-methyl-2-ethylhexanoic acid chloride and 108 parts of methoxydiphenylphosphine give 165 parts of 2-methyl-2-ethylhexanoyl-diphenylphosphine oxide as an oily crude product. Column chromatography over silica gel (eluant: a 3:1 mixture of toluene and ether) gives the product as a pale yellowish oil. Yield 154 parts (90% of theory).

出典と根拠

ORDレコード: ord-399f50cdad2d403f8f3f3bb360662317
出典データセット: uspto-grants-1982_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04324744

反応ノート

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