4-Nitro-2-trichloromethylbenzenesulfenyl chloride → (4-Nitro-2-trichloromethylphenyl)-(2-cyano-3-chlorophenyl)-disulfide

HRID 2285716ノート

反応式

HRID 2285716 の反応式
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10]Cl)=[C:6]([C:12]([Cl:15])([Cl:14])[Cl:13])[CH:5]=1)([O-:3])=[O:2].[C:16]([C:18]1[C:23]([Cl:24])=[CH:22][CH:21]=[CH:20][C:19]=1[SH:25])#[N:17]>C(OCC)C>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][S:25][C:19]2[CH:20]=[CH:21][CH:22]=[C:23]([Cl:24])[C:18]=2[C:16]#[N:17])=[C:6]([C:12]([Cl:15])([Cl:14])[Cl:13])[CH:5]=1)([O-:3])=[O:2]

参加物

4

反応物 2

HCID 127635554-Nitro-2-trichloromethylbenzenesulfenyl chlorideHCID 212247652-Chloro-6-sulfanylbenzonitrile

生成物 1

HCID 20544198(4-Nitro-2-trichloromethylphenyl)-(2-cyano-3-chlorophenyl)-disulfide収率 86.3%

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

30.7 g of 4-nitro-2-trichloromethylbenzenesulfenyl chloride in 500 ml of diethyl ether is reacted in a stirred apparatus with 17 g of 2-cyano-3-chlorothiophenol for 4 hours at 30° C. There is obtained 38 g (86% of theory) of (4-nitro-2-trichloromethylphenyl)-(2-cyano-3-chlorophenyl)-disulfide; m.p.: 137° C.

出典と根拠

ORDレコード
ord-382f6d68d4254a72a9fb334ed1edad9a
出典データセット
uspto-grants-1982_04
特許番号
US04324793

反応ノート

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