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Tetradecyltrimethylammonium → 2-(2,4-Dichlorophenyl)-2-[1-(1H-1,2,4-triazol-1-yl)cyclopropyl]oxirane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Tetradecyltrimethylammonium | HCID 14251 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | Iodide Ion | HCID 30165 | — |
| 反応物 | 1-(1H-1,2,4-Triazol-1-yl)cyclopropyl 2,4-dichlorophenyl ketone | HCID 21294612 | — |
| 溶媒 | 1,1,1-Trichloroethane | HCID 6278 | — |
| 生成物 | 2-(2,4-Dichlorophenyl)-2-[1-(1H-1,2,4-triazol-1-yl)cyclopropyl]oxirane | HCID 20230216 | — |
反応手順
1-(1-H-1,2,4-Triazol-1-yl)cyclopropyl 2,4-dichlorophenyl ketone (0.5 g, 1.8 mMole) was added to trimethylsulfphoxonium iodide (0.57 g, 2.6 mMole), cetrimide (0.02 g), 1,1,1-trichloroethane (10 ml) and aqueous sodium hydroxide solution (5 ml of 20%). The mixture was refluxed for twenty hours.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04618616 |
| 出典データセット | uspto-grants-1986_10 |
| ORD ID | ord-cf1b6c86002a44608be900afac2649bc |
| 出典メモ | uspto-grants-1986_10 |