Hydrochloric Acid → HCID 53704277、化合物

HRID 2290826ノート

反応式

HRID 2290826 の反応式
Cl.C([O:5][C:6]1[CH:7]=[C:8]([CH:16]=[CH:17][C:18](=[O:25])[CH:19]([CH3:24])[CH2:20][CH2:21][CH2:22][CH3:23])[CH:9]=[CH:10][C:11]=1[O:12]C(=O)C)(=O)C>>[OH:5][C:6]1[CH:7]=[C:8]([CH:16]=[CH:17][C:18](=[O:25])[CH:19]([CH3:24])[CH2:20][CH2:21][CH2:22][CH3:23])[CH:9]=[CH:10][C:11]=1[OH:12]

参加物

3

反応物 2

HCID 313Hydrochloric AcidHCID 54061909HCID 54061909、化合物

生成物 1

HCID 53704277HCID 53704277、化合物収率 93.7%

実験手順

A hydrochloric acid-acidified aqueous solution obtained by following the same procedure as in Example 27 using 1.0 g of 1-(3,4-diacetoxyphenyl)-4-methyl-1-octen-3-one, was extracted twice each time with 20 ml of ether. The extract was washed with water, dried over anhydrous magnesium sulfate, and concentrated under reduced pressure to provide 0.7 g of oily 1-(3,4-dihydroxyphenyl)-4-methyl-1-octen-3-one.

後処理

  1. customobtained
  2. extractionwas extracted twice each time with 20 ml of ether
  3. washThe extract was washed with water
  4. dry with materialdried over anhydrous magnesium sulfate
  5. concentrationconcentrated under reduced pressure

出典と根拠

ORDレコード
ord-f719c76bc21b4005b45154f29c6f404b
出典データセット
uspto-grants-1986_10
特許番号
US04618627

反応ノート

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