Ethanol → Diethyl Maleate

HRID 2291373

反応式

HRID 2291373 の反応式
[C:1]([O:8][CH2:9][CH3:10])(=[O:7])/[CH:2]=[CH:3]\[C:4]([O-:6])=[O:5].[CH2:11](O)[CH3:12]>>[C:4]([O:6][CH2:11][CH3:12])(=[O:5])/[CH:3]=[CH:2]\[C:1]([O:8][CH2:9][CH3:10])=[O:7]

参加物

3

反応物 2

HCID 702Ethanol2 回HCID 86733784(Z)-4-ethoxy-4-oxobut-2-enoate

生成物 1

HCID 5271566Diethyl Maleate

実験手順

In the plant of FIG. 6 maleic anhydride is supplied in line 401 to monoesterification reactor 402, to which is also supplied a stream containing ethanol in line 403. Reactor 402 is also fed by way of line 401 with a recycle stream from line 404 that contains recovered maleic anhydride and diethyl maleate. Monoesterification reactor 402 is provided with a stirrer 405, with a cooling coil 406 (which doubles as a steam heating coil at start up of the plant), and with a vent line 407. Maleic anhydride reacts with ethanol in reactor 402 to produce monoethyl maleate in the absence of a catalyst. The liquid reaction mixture from reactor 402 is discharged in line 408 and pumped by pump 409 to steam heater 410. Upstream from heater 410 it is admixed with two streams comprising further ethanol supplied in lines 411 and 412. The mixed stream flows on in line 413 to a primary esterification reactor 414 which contains a fixed bed of an acidic ion exchange resin, such as Amberlyst 16. Reaction between monoethyl maleate and ethanol to form diethyl maleate takes place in reactor 414.

後処理

  1. customThe liquid reaction mixture from reactor 402
  2. customThe mixed stream flows on in line 413 to a primary esterification reactor

出典と根拠

ORDレコード
ord-b30eff98a93e487eadaab8fdc3ce62b6
出典データセット
uspto-grants-1989_01
特許番号
US04795824

関連ノート

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