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Exifone → 2,2-Dimethyl-propionic acid 2,3-bis-(2,2-dimethyl-propionyloxy)-6-[3,4,5-tris-(2,2-dimethyl-propionyloxy)-benzoyl]-phenyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Exifone | HCID 40399 | — |
| 反応物 | Pivaloyl chloride | HCID 62493 | — |
| 溶媒 | Pyridine | HCID 1049 | — |
| 生成物 | 2,2-Dimethyl-propionic acid 2,3-bis-(2,2-dimethyl-propionyloxy)-6-[3,4,5-tris-(2,2-dimethyl-propionyloxy)-benzoyl]-phenyl ester | HCID 14010408 | — |
反応手順
100 mg of 3,4,5,4',5',6'-hexahydroxy benzophenone (0.00036 mole) and 450 MG (0.004 mole) of pivaloyl chloride were warmed to 50° C. in 20 mls of pyridine for 4 hrs. Solvent removed via N2 stream. Water added and extraction of product was done via CH2Cl2. The organic layer was washed with K2CO3 (5%) and dried over MgSo4. Solvent removal left an oil. 250 mg. (88%) yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04801610 |
| 出典データセット | uspto-grants-1989_01 |
| ORD ID | ord-8d2c2458b1184cd184c7b5162797bcff |
| 出典メモ | uspto-grants-1989_01 |