HCID 21475499、化合物 → HCID 21475503、化合物
反応式
[N+:1]([C:4]1C=C(N)C=[CH:8][C:9]=1NCC=C)([O-])=O.F[C:16]1[CH:21]=[CH:20][C:19]([N:22]([CH2:28][CH:29]([OH:32])[CH2:30][OH:31])[CH2:23][CH:24]([OH:27])[CH2:25][OH:26])=[CH:18][C:17]=1[N+:33]([O-:35])=[O:34]>>[N+:33]([C:17]1[CH:18]=[C:19]([N:22]([CH2:28][CH:29]([OH:32])[CH2:30][OH:31])[CH2:23][CH:24]([OH:27])[CH2:25][OH:26])[CH:20]=[CH:21][C:16]=1[NH:1][CH2:4][CH:9]=[CH2:8])([O-:35])=[O:34]参加物
3
実験手順
Synthesis as for compound 1, but with 4-fluoro-3-nitro-N,N-bis-(2,3-dihydroxypropyl)-aminobenzene instead of 4-fluoro-3-nitroaminobenzene. Working up: the reaction mixture was concentrated and the dark oil was dissolved in ethanol. Compound (3) was then precipitated with HCl gas in the form of the hydrochloride. Yellow crystals, melting point 154°-158° C.
後処理
- concentrationWorking up: the reaction mixture was concentrated
- dissolutionthe dark oil was dissolved in ethanol
- customCompound (3) was then precipitated with HCl gas in the form of the hydrochloride