Phosgene → Tetradecyl chloroformate
反応式
[C:1](Cl)([Cl:3])=[O:2].[CH2:5]([OH:19])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]>C1(C)C=CC=CC=1>[Cl:3][C:1]([O:19][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:2]参加物
4
実験手順
29 ml of a 20% toluene solution of phosgene (55.98 mmoles) was added to tetradecyl alcohol (4 g, 18.66 mmoles) and the reaction mixture was left to stand for 20 hours under stirring at room temperature. After solvent evaporation, the residue was taken up with hexane and evaporated to dryness (several times) to give 5.1 g product as colourless liquid.
後処理
- waitthe reaction mixture was left
- customAfter solvent evaporation
- customevaporated to dryness (several times)
出典と根拠
- ORDレコード
- ord-2d13dd51f1cf434baf640ddf914ee0aa
- 出典データセット
- uspto-grants-2009_07
- 特許番号
- USRE040861E1
反応ノート
読み込み中…