関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 2,4-Dinitroiodobenzene | HCID 69730 | — |
| 反応物 | Diethyl 5-tributylstannyl-2-furanphosphonate | HCID 22280515 | — |
| 触媒 | Tetrakis(triphenylphosphine)palladium | HCID 11979704 | — |
| 溶媒 | 1,4-Dioxane | HCID 31275 | — |
| 生成物 | Diethyl 5-(3,5-dinitrophenyl)-2-furanphosphonate | HCID 22349210 | — |
反応手順
A mixture of diethyl 5-tributylstannyl-2-furanphosphonate (1 mmol), 1-iodo-2,4-dinitrobenzene (1 mmol) and tetrakis(triphenylphosphine)-palladium(0) (0.05 mmol) in 6 mL of dioxane was heated at 80° C. for 16 h. Evaporation of solvent and chromatography provided diethyl 5-(3,5-dinitrophenyl)-2-furanphosphonate as solid foam.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07563774B2 |
|---|
| 出典データセット | uspto-grants-2009_07 |
|---|
| ORD ID | ord-9ba19b201669434ead85defe26c61962 |
|---|
| 出典メモ | uspto-grants-2009_07 |
|---|
