Aluminium lithium hydride → HCID 54085391、化合物

HRID 2295702ノート

反応式

HRID 2295702 の反応式
[CH3:1][C:2]([CH3:13])([C:4](=[O:12])[CH2:5][CH2:6][CH:7]=[CH:8][CH:9]=[CH:10][CH3:11])[CH3:3].[H-].[Al+3].[Li+].[H-].[H-].[H-]>CCOCC>[CH3:13][C:2]([CH3:3])([CH:4]([OH:12])[CH2:5][CH2:6][CH:7]=[CH:8][CH:9]=[CH:10][CH3:11])[CH3:1]

参加物

4

反応物 2

HCID 21226445Aluminium lithium hydrideHCID 537861612,2-Dimethyl-6,8-decadien-3-one

生成物 1

HCID 54085391HCID 54085391、化合物収率 47.6%

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

According to the procedure described in Example 3, by reducing 16.2 g of 2,2-dimethyl-6,8-decadien-3-one with 3.4 g of lithium aluminium hydride in 250 ml of dry ether there are obtained 17 g of crude product which gave 7.8 g of pure 2,2-dimethyl-6,8-decadien-3-ol by fractional distillation.

後処理

  1. customare obtained 17 g of crude product which

出典と根拠

ORDレコード
ord-d0a9d59f731e496495dee6131a4b4c02
出典データセット
uspto-grants-1984_01
特許番号
US04426321

反応ノート

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