Toluene → HCID 54405367、化合物

反応式

ClCC=CC=C.[CH2:7]([C:10]([CH2:12][CH2:13][CH3:14])=[O:11])[CH2:8][CH3:9].[OH-].[K+].[C:17]1([CH3:23])[CH:22]=[CH:21]C=[CH:19][CH:18]=1>>[CH2:8]([CH:7]([CH2:21][CH:22]=[C:17]([CH3:23])[CH:18]=[CH2:19])[C:10](=[O:11])[CH2:12][CH2:13][CH3:14])[CH3:9]

参加物

反応物 4

HCID 1140Toluene

HCID 14797Potassium Hydroxide

HCID 312464-Heptanone

HCID 53837795HCID 53837795、化合物

生成物 1

HCID 54405367HCID 54405367、化合物

実験手順

According to the procedure described in Example 1, from 116.6 g of 1-chloro-2,4-pentadiene and 114.2 g of dipropyl ketone (heptan-4-one) in the presence of 200 g of powdered potassium hydroxide in 600 ml of toluene there are obtained 91.9 g of crude 5-ethyl-8-methyl-7,9-decadien-4-one which are subjected to a fractional distillation.