Butyl phenyl ether → HCID 20472103、化合物

HRID 2296263

反応式

HRID 2296263 の反応式
[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[P:12]12(SP3(SP(SP(S3)(S1)=S)(=S)[S:14]2)=S)=[S:13]>CCCCCC>[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][C:9]([P:12](=[S:14])=[S:13])=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4]

参加物

4

反応物 2

HCID 14311Butyl phenyl etherHCID 14817Phosphorus sulfide (P2S5)

生成物 1

HCID 20472103HCID 20472103、化合物

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒

実験手順

n-Butyloxybenzene (Ic) and P4S10 (in a molar ratio of 10:1) were stirred for six hours at 150° C. under anhydrous conditions. The mixture was cooled, hexane was added, and the reaction flask was left for two days at 5° C. The resulting precipitate was recovered by filtration, washed with anhydrous hexane and dried. The yield of product was 37% of theory; after recrystallization from chloroform/petroleum ether it melted at 142°-4° C. Its solubility in tetrahydrofuran was found to be 5 gms/100 ml at room temperature.

後処理

  1. temperatureThe mixture was cooled
  2. filtrationThe resulting precipitate was recovered by filtration
  3. washwashed with anhydrous hexane
  4. customdried
  5. customafter recrystallization from chloroform/petroleum ether it melted at 142°-4° C
  6. customat room temperature

出典と根拠

ORDレコード
ord-528df5a62ab441a5872b6794550b2c2b
出典データセット
uspto-grants-1984_01
特許番号
US04428889

関連ノート

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