Cyclohexylhydroxylamine → alpha-(2,4,6-Triethoxyphenyl)-N-cyclohexylnitrone

反応式

[CH2:1]([O:3][C:4]1[CH:11]=[C:10]([O:12][CH2:13][CH3:14])[CH:9]=[C:8]([O:15][CH2:16][CH3:17])[C:5]=1[CH:6]=O)[CH3:2].[CH:18]1([NH:24][OH:25])[CH2:23][CH2:22][CH2:21][CH2:20][CH2:19]1>>[CH2:1]([O:3][C:4]1[CH:11]=[C:10]([O:12][CH2:13][CH3:14])[CH:9]=[C:8]([O:15][CH2:16][CH3:17])[C:5]=1[CH:6]=[N+:24]([CH:18]1[CH2:23][CH2:22][CH2:21][CH2:20][CH2:19]1)[O-:25])[CH3:2]

参加物

反応物 2

HCID 72935Cyclohexylhydroxylamine

HCID 2897412,4,6-Triethoxybenzaldehyde

生成物 1

HCID 86587902alpha-(2,4,6-Triethoxyphenyl)-N-cyclohexylnitrone

実験手順

The title compound was prepared according to the procedure described in Example 11 using 2,4,6-triethoxybenzaldehyde and N-cyclohexylhydroxylamine. The title compound was isolated in 87.4% yield as a solid, m.p. 145.7° C.

後処理

customThe title compound was prepared

出典と根拠

ORDレコード: ord-d0d02780322c49a4bff013f18f2a35ca
出典データセット: uspto-grants-2002_08
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06433008B1

反応ノート

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