化工社化工社 化学情報印刷レポート · 研究参考用
Diethyl (1-cyanoethyl)phosphonate → 2-(3,3,5,5-Tetramethylcyclohexylidene)propionitrile
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Diethyl (1-cyanoethyl)phosphonate | HCID 282103 | — |
| 反応物 | 3,3,5,5-Tetramethylcyclohexylideneacetonitrile | HCID 22630150 | — |
| 生成物 | 2-(3,3,5,5-Tetramethylcyclohexylidene)propionitrile | HCID 22630158 | 41% |
反応手順
Prepared according to the procedure for compound 20 (Example 10, a) using diethyl (1-cyanoethyl)phosphonate. Nitrile 21 obtained as a colorless oil with 41% yield. 1H-NMR: (CDCl3, TMS): 0.96 and 1.00 (total 12H, both s, c-Hex-3,5-CH3); 1.34 (2H, s, c-Hex-4-CH2); 1.91 (3H, s, propionitrile-3-CH3); 2.04 and 2.28 ppm (total 4H, both s, c-Hex-2,6-CH2).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06828462B2 |
| 出典データセット | uspto-grants-2004_12 |
| ORD ID | ord-21238243ee2d4cc49273a5b3675f7004 |
| 出典メモ | uspto-grants-2004_12 |