化工社化工社 化学情報印刷レポート · 研究参考用
Water → 1-[2-(Benzyloxy)-6-hydroxyphenyl]ethan-1-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Benzyl Bromide | HCID 7498 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | 2',6'-Dihydroxyacetophenone | HCID 69687 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | 1-[2-(Benzyloxy)-6-hydroxyphenyl]ethan-1-one | HCID 2775187 | — |
反応手順
To a mixture of 2′,6′-dihydroxyacetophenone (4 g) and potassium carbonate (3.82 g) in acetone (40 mL) was added benzyl bromide (3.13 mL), and the mixture was stirred at room temperature overnight. The reaction mixture was poured into water, and the precipitated crystals were collected by filtration. The crystals were washed with water and n-hexane, and dried under reduced pressure to give the title compound (3.67 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07566699B2 |
| 出典データセット | uspto-grants-2009_07 |
| ORD ID | ord-ad510b46ab0447c5abe0f9bfcbc6058e |
| 出典メモ | uspto-grants-2009_07 |