Dichloromethane → HCID 14877725、化合物

反応式

ClCCl.[CH:4]1([CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][O:22][CH2:23][CH:24]([CH2:27][OH:28])[O:25][CH3:26])[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5]1.[CH3:29][S:30](Cl)(=[O:32])=[O:31]>C(N(CC)CC)C>[CH3:29][S:30]([O:28][CH2:27][CH:24]([O:25][CH3:26])[CH2:23][O:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH:4]1[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5]1)(=[O:32])=[O:31]

参加物

実験手順

To 100 ml of dichloromethane are added 10.8 g of 1-(12-cyclohexyldodecyl)-2-methylglycerine and 4.42 ml of triethylamine, to which 3.64 g of methanesulfonyl chloride is added dropwise with stirring under ice cooling. Then, the mixture is stirred at room temperature for 2 hours to complete the reaction. The reaction mixture is washed with water, an aqueous sodium bicarbonate solution and water, and dried. The solvent is removed by distillation to leave 10.42 g of the captioned compound.