Hydroquinone → 2,2-Bis(p-(3-phenoxy-2-glycidyloxypropyloxy)phenyl)-propane

HRID 231386

反応式

HRID 231386 の反応式
[C:1]1([CH:8]=[CH:7][CH:6]=[C:4]([OH:5])[CH:3]=1)O.[C:9]1([CH:16]=[CH:15][C:13]([OH:14])=[CH:12][CH:11]=1)O.C[C:18]1[C:24](O)=[CH:23][CH:22]=[CH:21][C:19]=1[OH:20].OC1C=C[C:30]([C:31]([C:33]2[CH:38]=[CH:37][C:36]([OH:39])=[CH:35][CH:34]=2)=O)=CC=1.OC1C2C(=[C:48]([OH:53])[CH:49]=[CH:50]C=2)C=CC=1.OC1C=CC(C(C2[CH:69]=[CH:68][C:67]([OH:70])=CC=2)(C)C)=CC=1.[OH:71][C:72]1[CH:77]=CC(C(C2C=CC(O)=CC=2)CC)=C[CH:73]=1.[OH:88][C:89]1[CH:94]=CC(C(C2C=CC(O)=CC=2)C)=C[CH:90]=1.O[C:105]1C=CC(C(C2C=CC(O)=CC=2)C(C)C)=CC=1.OC1C=CC(C(C2C=CC(O)=CC=2)(CC)C)=CC=1.OC1C=CC(C(C2C=CC(O)=CC=2C)(C)C)=C(C)C=1.OC1C=CC(C(C2C=CC(O)=CC=2)(CC)CC)=CC=1.OC1C=CC(C(C2C=CC(O)=CC=2)C(CC)CCCC)=CC=1.OC1C=CC(CC2C=CC(O)=CC=2)=CC=1>>[O:5]([CH2:90][CH:89]([O:88][CH2:50][CH:49]1[O:53][CH2:48]1)[CH2:94][O:14][C:13]1[CH:15]=[CH:16][C:9]([C:31]([C:33]2[CH:34]=[CH:35][C:36]([O:39][CH2:73][CH:72]([O:71][CH2:69][CH:68]3[O:70][CH2:67]3)[CH2:77][O:20][C:19]3[CH:18]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:37][CH:38]=2)([CH3:30])[CH3:105])=[CH:11][CH:12]=1)[C:4]1[CH:6]=[CH:7][CH:8]=[CH:1][CH:3]=1

参加物

15

反応物 14

HCID 785HydroquinoneHCID 5054ResorcinolHCID 6623Bisphenol AHCID 67491,5-DihydroxynaphthaleneHCID 118432-MethylresorcinolHCID 12111Bis(4-hydroxyphenyl)methaneHCID 66166Bisphenol BHCID 691504,4'-DihydroxybenzophenoneHCID 2269694,4'-(2-Methylpropylidene)bisphenol2 回HCID 608116Bisphenol EHCID 22885033,3-Bis(4-hydroxyphenyl)pentaneHCID 42010814,4'-Propane-1,1-diyldiphenolHCID 137824874-[2-Ethyl-1-(4-hydroxyphenyl)hexyl]phenolHCID 139812092,2-Bis(4-hydroxy-2-methylphenyl)propane

生成物 1

HCID 226006442,2-Bis(p-(3-phenoxy-2-glycidyloxypropyloxy)phenyl)-propane

実験手順

Suitable polyethers of polyhydric phenols excluding the diglycidyl ethers noted above, include for example, the polyglycidyl polyethers of dihydric phenols including mononuclear phenols such as resorcinol, catachol, hydroquinone and methyl resorcinol and polynuclear phenols such as 4,4'-dihydroxy benzophenone, 1,5-dihydroxy naphthalene and particularly the alkylene bis-phenols such as 2,2-bis(4-hydroxyphenyl)propane, 1,1-bis(4-hydroxyphenyl)propane, 1,1-bis(4-hydroxyphenyl)ethane, 1,1-bis(4-hydroxyphenyl)isobutane, 2,2-bis(4-hydroxyphenyl)butane, 2,2-bis(4-hydroxy-2-methylphenyl)propane, 1,1-bis(4-hydroxyphenyl)-2-methyl propane, 3,3-bis(4-hydroxyphenyl)pentane, 1,1-bis(4-hydroxyphenyl)2-ethylhexane, and bis(4-hydroxyphenyl)methane.

出典と根拠

ORDレコード
ord-0414fbd0bc7b42eaa0af1d4210d1c00e
出典データセット
uspto-grants-1989_07
特許番号
US04845172

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