Dimethylformamide → 2-Thenylamine, N,N-bis(2-chloroethyl)-, hydrochloride
反応式
[CH:1]1[CH:5]=[C:4]([CH2:6][N:7]([CH2:11][CH2:12][Cl:13])[CH2:8][CH2:9][Cl:10])[S:3][CH:2]=1.[ClH:14].[Br-].CN(C=O)C.C(N(CC)CC)C.CC(OCC1C2C(=CC=CC=2)C(COC(C)=O)=C2C=1C=CC=C2)=O>O=O>[CH:1]1[CH:5]=[C:4]([CH2:6][N:7]([CH2:11][CH2:12][Cl:13])[CH2:8][CH2:9][Cl:10])[S:3][CH:2]=1.[ClH:14]参加物
6
実験手順
One millimole of DCTA-bromide was added to 5 ml of DMF containing 0.2 ml of 1,2-dithioethylene and 0.5 ml of triethylamine. The mixture was incubated under argon for 2 hours at 60°-70° C. After reaction the mixture was diluted with oxygen-free H2O to 50 ml, the pH was adjusted to 4.0-4.5 with glacial acetic
後処理
- customAfter reaction the mixture
出典と根拠
- ORDレコード
- ord-000a47c865de4642a35a7aa65463289b
- 出典データセット
- uspto-grants-1989_07
- 特許番号
- US04849505
反応ノート
読み込み中…