Phenol, 4-[2-(4-nitrophenyl)ethenyl]- → 6-{4-[2-(4-Nitrophenyl)ethenyl]phenoxy}hexan-1-OL

HRID 232188

反応式

HRID 232188 の反応式
[K].[OH:2][C:3]1[CH:8]=[CH:7][C:6]([CH:9]=[CH:10][C:11]2[CH:16]=[CH:15][C:14]([N+:17]([O-:19])=[O:18])=[CH:13][CH:12]=2)=[CH:5][CH:4]=1.I[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][OH:27]>>[OH:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][O:2][C:3]1[CH:8]=[CH:7][C:6]([CH:9]=[CH:10][C:11]2[CH:16]=[CH:15][C:14]([N+:17]([O-:19])=[O:18])=[CH:13][CH:12]=2)=[CH:5][CH:4]=1

参加物

4

反応物 3

HCID 139676Phenol, 4-[2-(4-nitrophenyl)ethenyl]-HCID 5462222PotassiumHCID 130890816-Iodo-1-hexanol

生成物 1

HCID 539381646-{4-[2-(4-Nitrophenyl)ethenyl]phenoxy}hexan-1-OL

実験手順

Employing the procedure of Example I(A), 14 g (0.05M) of the potassium salt of 4-hydroxy-4'-nitrostilbene and 14 g (0.06M) of 6-iodo-1-hexanol are reacted. The resultant product is recrystallized from toluene, m.p. 154°-157° C.

後処理

  1. customare reacted
  2. customThe resultant product is recrystallized from toluene, m.p. 154°-157° C.

出典と根拠

ORDレコード
ord-570933961f3d452fb9b4f91af9a381f1
出典データセット
uspto-grants-1989_07
特許番号
US04851502

関連ノート

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