Methane → Distearyl Ether

HRID 232530

反応式

HRID 232530 の反応式
[CH2:1](Br)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[OH-:20].[K+].[CH4:22]>C1(C)C=CC=CC=1>[CH2:1]([O:20][CH2:22][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

参加物

5

反応物 3

HCID 297MethaneHCID 82181-Bromooctadecane2 回HCID 14797Potassium Hydroxide

生成物 1

HCID 80526Distearyl Ether

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
60 °C

実験手順

Distearyl ether was synthesized by reacting stearyl bromide (Sigma) with PEG-900 in the presence of potassium hydroxide. Stearyl bromide (4.168 g in 10 ml toluene) was slowly added with stirring to 4.64 g of PEG-900 in 10 ml of toluene at 45° C. The mixture was then stirred at 60° C. for 30 min. and refluxed for 6 hrs. The final product was treated with charcoal, filtered and isolated from toluene.

後処理

  1. customDistearyl ether was synthesized
  2. temperaturerefluxed for 6 hrs
  3. filtrationfiltered
  4. customisolated from toluene

出典と根拠

ORDレコード
ord-3cf91bd8c78b45ccbe106bf28b4ddeb1
出典データセット
uspto-grants-1997_01
特許番号
US05591715

関連ノート

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