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Phosphate → 2-Amino-6-tert-butyl-benzothiazole-4-thiol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Phosphate | HCID 1061 | — |
| 反応物 | D-1,4-Dithiothreitol | HCID 446094 | — |
| 反応物 | 6-Tert-butyl-4-thiocyanato-benzothiazol-2-yl-amine | HCID 15473842 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 2-Amino-6-tert-butyl-benzothiazole-4-thiol | HCID 22572780 | — |
反応手順
The title compound was prepared according to General Method 14 using 6-tert-butyl-4-thiocyanato-benzothiazol-2-yl-amine (Example L-6; 2.0 g. 7.6 mmol), dithiothreitol (4.6 g, 30 mmol), phosphate buffer of pH 7 (10 mL), and EtOH (50 mL). The crude product was used further without any purification. MS (APCI): 239 (M+H).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06852711B2 |
| 出典データセット | uspto-grants-2005_02 |
| ORD ID | ord-c023bb652b76466495c6fd9c9529320f |
| 出典メモ | uspto-grants-2005_02 |