Potassium Carbonate → 5-(tert-Butyl)-2-nitroaniline
反応式
[C:1]([C:5]1[CH:6]=[CH:7][C:8]([N+:18]([O-:20])=[O:19])=[C:9]([NH:11]C(=O)C(F)(F)F)[CH:10]=1)([CH3:4])([CH3:3])[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[C:1]([C:5]1[CH:6]=[CH:7][C:8]([N+:18]([O-:20])=[O:19])=[C:9]([NH2:11])[CH:10]=1)([CH3:4])([CH3:2])[CH3:3]参加物
4
実験手順
The title compound was prepared as outlined in Example PP-1 from N-(5-tert-butyl-2-nitro-phenyl)-2,2,2-trifluoro-acetamide (prepared in Example OO-2; 248 g, 855 mmol), MeOH (500 mL), and 7% aqueous potassium carbonate solution. The crude product was used without any purification. MS(APCI): 195 (M+H).
後処理
- customThe crude product was used without any purification
出典と根拠
- ORDレコード
- ord-c77133d2549b45b9a0778b01884be175
- 出典データセット
- uspto-grants-2005_02
- 特許番号
- US06852711B2
反応ノート
読み込み中…