Ethyl sulfide → HCID 86743413、化合物

反応式

[CH2:1]([S:3][CH2:4][CH3:5])[CH3:2].[CH2:6]([I:28])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27]>>[I-:28].[CH2:1]([S+:3]([CH2:4][CH3:5])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[CH3:2]

参加物

反応物 2

HCID 9609Ethyl sulfide

HCID 132572191-Iododocosane

生成物 1

HCID 86743413HCID 86743413、化合物

実験手順

Diethyl sulphide is quaternized by docosyl iodide in order to obtain diethyldocosylsulphonium iodide. This iodide is then placed in an alcoholic solution with an equivalent of the TCNQ lithium salt. This gives crystals, which are recrystallized in alcohol. These crystals are constituted by the simple tetracyanoquinodimethane diethyl docosyl sulphonium salt of formula: ##STR4##

出典と根拠

ORDレコード: ord-c8b229f5aef446ccb6a3461411dca00c
出典データセット: uspto-grants-1989_10
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04871680

反応ノート

読み込み中…

参加物