Dodecanenitrile → 4-Ethyl-2-undecyl-2-oxazoline

HRID 2352195

反応式

HRID 2352195 の反応式
[CH2:1]([C:12]#[N:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH3:14][CH2:15][CH:16](N)[CH2:17][OH:18]>C(O)CCC.O.O.C([O-])(=O)C.[Cd+2].C([O-])(=O)C>[CH2:15]([CH:16]1[CH2:17][O:18][C:12]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])=[N:13]1)[CH3:14]

参加物

5

反応物 2

HCID 17092DodecanenitrileHCID 221292-Amino-1-butanol

生成物 1

HCID 2268484-Ethyl-2-undecyl-2-oxazoline収率 89.6%

試薬・触媒・溶媒 2

HCID 6537495Cadmium acetate, dihydrate触媒HCID 2631-Butanol溶媒

実験手順

25 g (137.9 mmoles) of undecyl cyanide was treated with 15.2 ml (165 mmoles) of DL-2-amino-1-butanol in presence of 919 mg (3.54 mmoles) of cadmium acetate dihydrate in 1-butanol as outlined under Example 1. 31.31g (89.6%) of product was obtained on distillation at 124°-125°C./1.2-1.4mmHg.

出典と根拠

ORDレコード
ord-1faa8d722da24280a9e2d67bb1575a23
出典データセット
uspto-grants-1989_10
特許番号
US04876249

関連ノート

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