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6-Methylquinoline → 4-Quinolinecarboxaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 6-Methylquinoline | HCID 7059 | — |
| 反応物 | 4-Methylquinoline | HCID 10285 | — |
| 反応物 | 2,6-Dimethylquinoline | HCID 13414 | — |
| 反応物 | Selenium Dioxide | HCID 24007 | — |
| 反応物 | 6-Quinolinecarbaldehyde | HCID 765653 | — |
| 生成物 | 4-Quinolinecarboxaldehyde | HCID 78072 | — |
| 生成物 | 6-Methyl-2-quinolinecarboxaldehyde | HCID 14645230 | — |
反応手順
6-Methylquinoline-2-carboxaldehyde and quinoline-4-carboxaldehyde were prepared from 2,6-dimethylquinoline and 4-methylquinoline respectively by selenium dioxide oxidation following essentially the same procedures as those described in Organic Reactions, vol 24, ch. 4. Quinoline-6-carboxaldehyde was similarly prepared from 6-methylquinoline following essentially the same procedure as that described in J. Gen. chem. USSR, 1944, 14, 330 (Chem. Abstr., 1945, 39, 40772)
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04640708 |
| 出典データセット | uspto-grants-1987_02 |
| ORD ID | ord-6a821a3559c24adf8b998b18f4b3561a |
| 出典メモ | uspto-grants-1987_02 |