Bromotrimethylsilane → HCID 86625204、化合物
反応式
C([O:3][P:4]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][O:25][C:26]1[C:43]([O:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH3:50])=[CH:42][C:41]2[C:40]3[C:35](=[CH:36][C:37]([O:58][CH2:59][CH2:60][CH2:61][CH2:62][CH2:63][CH3:64])=[C:38]([O:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH3:57])[CH:39]=3)[C:34]3[C:29](=[CH:30][C:31]([O:72][CH2:73][CH2:74][CH2:75][CH2:76][CH2:77][CH3:78])=[C:32]([O:65][CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH3:71])[CH:33]=3)[C:28]=2[CH:27]=1)(=[O:8])[O:5]CC)C.C[Si](Br)(C)C>C(Cl)Cl>[CH2:45]([O:44][C:43]1[C:26]([O:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][P:4](=[O:3])([OH:8])[OH:5])=[CH:27][C:28]2[C:29]3[C:34]([C:35]4[C:40]([C:41]=2[CH:42]=1)=[CH:39][C:38]([O:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH3:57])=[C:37]([O:58][CH2:59][CH2:60][CH2:61][CH2:62][CH2:63][CH3:64])[CH:36]=4)=[CH:33][C:32]([O:65][CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH3:71])=[C:31]([O:72][CH2:73][CH2:74][CH2:75][CH2:76][CH2:77][CH3:78])[CH:30]=3)[CH2:46][CH2:47][CH2:48][CH2:49][CH3:50]参加物
4
実験手順
In 15 mL of methylene chloride, 2.0 g (1.8 mmol) of [16-(3,6,7,10,11-pentakishexyloxytriphenylene-2-yloxy)-hexadecyl]-phosphonic acid diethylester was dissolved, and 1.2 mL of trimethylsilylbromide was added to the solution under argon. Then, the solution was stirred at ambient temperature. After 27 hours, the solvent and excess trimethylsilylbromide were evaporated, and the residue was dissolved in 100 mL of ethanol. The solution was stirred at ambient temperature for 48 hours, and then the solvent was evaporated. As a result, 1.9 g of a white solid was obtained.