関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Boron tribromide | HCID 25134 | — |
| 反応物 | 4-Methoxy-1-tetradecyl-benzene | HCID 20218714 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | Tetradecylphenol | HCID 116800 | 101.7% |
反応手順
Boron tribromide was added dropwise, under argon to an about -78° C. solution of about 12.16 g of 4-methoxy-1-tetradecyl-benzene in about 125 ml of methylene chloride. The reaction was stirred for about 21/2 hours at about -78° C., then water was added dropwise, the organic layer separated, washed with sodium bicarbonate solution and evaporated, giving about 11.8 g of the desired title compound, mp 70°-71° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04640913 |
|---|
| 出典データセット | uspto-grants-1987_02 |
|---|
| ORD ID | ord-f9007c6b1efb48c18a61a71b6654494a |
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| 出典メモ | uspto-grants-1987_02 |
|---|
