Acetyl chloride → N-[3-(4-Methyl-2-nitro-phenylsulfanyl)-phenyl]-acetamide
反応式
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:10]=[C:11]([NH2:15])[CH:12]=[CH:13][CH:14]=2)=[C:4]([N+:16]([O-:18])=[O:17])[CH:3]=1.[C:19](Cl)(=[O:21])[CH3:20]>C(Cl)Cl>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:10]=[C:11]([NH:15][C:19](=[O:21])[CH3:20])[CH:12]=[CH:13][CH:14]=2)=[C:4]([N+:16]([O-:18])=[O:17])[CH:3]=1参加物
4
実験手順
The product from Example 71a (650 mg, 2.50 mmol) was dissolved in DCM and acetyl chloride (196 mg, 2.50 mmol) was added. Allowed to stir at room temperature for 1 h, at which time a solid was collected by filtration providing the title compound (690 mg, 61%)
後処理
- filtrationwas collected by filtration
出典と根拠
- ORDレコード
- ord-20d492e083994205a41b66ea719289d2
- 出典データセット
- uspto-grants-2010_07
- 特許番号
- US07763731B2
反応ノート
読み込み中…