関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 4-Chloro-alpha,alpha,alpha-trifluoro-3-nitrotoluene | HCID 8462 | — |
| 反応物 | Carbonate Ion | HCID 19660 | — |
| 反応物 | Carbonic acid, methyl phenyl ester | HCID 139482 | — |
| 反応物 | Tbpb | HCID 10092649 | — |
| 生成物 | 2-Nitro-1-phenoxy-4-(trifluoromethyl)benzene | HCID 245942 | 99% |
反応手順
A mixture of 3.8 g of methyl phenyl carbonate, 5.64 g of 4-chloro-3-nitrobenzotrifluoride, and 0.17 g of TBPB was heated at 150° C. for 1 hour. All of the carbonate was converted with a 99 percent yield of 2-nitro-4-trifluoromethylphenyl phenyl ether. Distillation of the product yielded 6.65 g (94 percent) of the ether, b.p. 148°-9° C./2 mm.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04642349 |
|---|
| 出典データセット | uspto-grants-1987_02 |
|---|
| ORD ID | ord-98fb5941a208442cbdd380a63fbbe737 |
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| 出典メモ | uspto-grants-1987_02 |
|---|
