Ammonia → 3-Amino-1,2,4-triazine mesylate

HRID 2361859ノート

反応式

HRID 2361859 の反応式
C(OC1C=C(C=[CH:17][CH:18]=1)C(OC)=O)C1C=CC=CC=1.[S:19]([OH:23])(=[O:22])(=[O:21])[CH3:20].S(O)(=O)(=O)C.[NH2:29][NH:30][C:31]([NH2:33])=[NH:32].N>>[S:19]([OH:23])(=[O:22])(=[O:21])[CH3:20].[NH2:33][C:31]1[N:30]=[N:29][CH:17]=[CH:18][N:32]=1

参加物

4

反応物 3

HCID 222AmmoniaHCID 13368031Methyl 3-(benzyloxy)benzoateHCID 178505340HCID 178505340、化合物

生成物 1

HCID 866497313-Amino-1,2,4-triazine mesylate

実験手順

Prepared by reacting acenaphthenequinone (3) with aminoguanidine bismesylate for 24 hrs using the above procedure except that the basification step with ammonia was omitted. The title compound was obtained as bright yellow prisms in 83.2%, mpt=264-266° (froth)

後処理

  1. customPrepared
  2. customfor 24 hrs

出典と根拠

ORDレコード
ord-be71e0b7da95491687df91d7870b06c0
出典データセット
uspto-grants-2014_04
特許番号
US08691818B2

反応ノート

読み込み中…