化工社化工社 化学情報印刷レポート · 研究参考用
Catechol → Ethyl o-phenylenephosphate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Catechol | HCID 289 | — |
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | Ethyl dichlorophosphate | HCID 15158 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | Ethyl o-phenylenephosphate | HCID 11820088 | 95.1% |
反応手順
Pyrocatechol (1.249 g, 11.35 mM) was dissolved in 42 ml of ether and, using 2.297 g (22.70 mM) of triethylamine and 1.849 g (11.35 mM) of ethyl dichlorophosphate, the reaction was carried out at -40° C. to -35° C. and the reaction mixture treated in the same manner as in Reference Example 1. There was obtained 2.159 g (95.0% yield) of ethyl o-phenylene phosphate as a colorless viscous oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04642365 |
| 出典データセット | uspto-grants-1987_02 |
| ORD ID | ord-5614493c1a0c4f8f99a799246d8cd8e7 |
| 出典メモ | uspto-grants-1987_02 |