反応式
[CH2:1]=[CH:2][CH:3]=[CH2:4].S1(CCCC1)(=O)=[O:6]>>[CH2:1]=[CH:2][CH:3]([OH:6])[CH3:4].[CH2:1]([OH:6])[CH:2]=[CH:3][CH3:4]参加物
4
反応条件
- 温度
- 100 °C
実験手順
In accordance with Example 1, a homogeneous solution of 6.2 grams (0.11 moles) of butadiene and 100 milliliters of a 65 volume percent aqueous sulfolane solution were reacted in the presence of a cation exchanger sold under the trademark Lewatit SPC 118 at a temperature of 100° C. After agitating at 100° C. for 6 hours, 76 percent of the mixture had reacted. A yield of 60 percent 1-butene-3-ol and a yield of 26 percent 2-butene-1-ol (crotylalcohol) was obtained.
出典と根拠
- ORDレコード
- ord-aa74cbbdce7045b8b53dc7029ba5d8d2
- 出典データセット
- uspto-grants-1987_02
- 特許番号
- US04645863
関連ノート
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