Ethylene → 1-Hexene

HRID 2367722

反応式

HRID 2367722 の反応式
C=C.[CH2:3]=[CH:4][CH2:5][CH2:6][CH2:7][CH3:8]>>[CH2:3]=[CH2:4].[CH2:3]=[CH:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH2:3]=[CH:4][CH2:5][CH2:6][CH2:7][CH3:8]

参加物

4

反応物 2

HCID 6325EthyleneHCID 115971-Hexene2 回

生成物 2

HCID 115971-HexeneHCID 168324Ethene--hex-1-ene (1/1)

実験手順

Using a stirring-type autoclave-type continuous reactor with an inner volume of 1.5 L, a mixture of ethylene and 1-hexene, as a raw material gas, was continuously supplied in a rate of 40 kg/hr, so that the composition of 1-hexene was 75% by weight, under maintaining pressure inside the reactor at 130 MPa. In addition, the above catalyst solution was supplied continuously by adjusting supply amount thereof so as to maintain polymerization temperature at 150° C. Production amount of the polymer was about 4.3 kg per hour. After completion of the reaction, the ethylene•1-hexene copolymer (PE-1), with a content of 1-hexene of 24% by weight, an MFR of 35 g/10 min, a density of 0.880 g/cm3, and a Mz/Mn of 3.7, was obtained.

後処理

  1. temperatureunder maintaining pressure inside the reactor at 130 MPa
  2. temperatureso as to maintain
  3. custompolymerization temperature at 150° C
  4. customAfter completion of the reaction

出典と根拠

ORDレコード
ord-f3611dc3a1c24601b8ca9b5782248957
出典データセット
uspto-grants-2014_04
特許番号
US08697984B2

関連ノート

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