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Ethylene → 1-Hexene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethylene | HCID 6325 | — |
| 反応物 | 1-Hexene | HCID 11597 | — |
| 生成物 | 1-Hexene | HCID 11597 | — |
| 生成物 | Ethene--hex-1-ene (1/1) | HCID 168324 | — |
反応手順
Using a stirring-type autoclave-type continuous reactor with an inner volume of 1.5 L, a mixture of ethylene and 1-hexene, as a raw material gas, was continuously supplied in a rate of 40 kg/hr, so that the composition of 1-hexene was 75% by weight, under maintaining pressure inside the reactor at 130 MPa. In addition, the above catalyst solution was supplied continuously by adjusting supply amount thereof so as to maintain polymerization temperature at 150° C. Production amount of the polymer was about 4.3 kg per hour. After completion of the reaction, the ethylene•1-hexene copolymer (PE-1), with a content of 1-hexene of 24% by weight, an MFR of 35 g/10 min, a density of 0.880 g/cm3, and a Mz/Mn of 3.7, was obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08697984B2 |
| 出典データセット | uspto-grants-2014_04 |
| ORD ID | ord-f3611dc3a1c24601b8ca9b5782248957 |
| 出典メモ | uspto-grants-2014_04 |