関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Ethylene | HCID 6325 | — |
| 反応物 | 2-Methylquinoline | HCID 7060 | — |
| 反応物 | Nitrobenzene | HCID 7416 | — |
| 生成物 | Aniline | HCID 6115 | 7.1% |
| 生成物 | Nitrobenzene | HCID 7416 | — |
反応手順
Twenty grams of nitrobenzene and 1.1 grams of iodo (4-iodophenyl) bis(triphenylphosphine)-palladium was placed in a 300 ml. stainless steel rocking autoclave. This was sealed and pressurized with ethylene to 600 psi and heated to 160° C. This temperature was maintained for 17 hours. The autoclave was then cooled and vented. After opening the vessel the reaction mixture was analyzed by gas chromatography. This analysis showed that 6.8 grams of 2-methylquinoline (54.0% efficiency) was obtained together with 0.6 grams of aniline (7.1% efficiency) and 7 grams of unreacted nitrobenzene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04157445 |
|---|
| 出典データセット | uspto-grants-1979_06 |
|---|
| ORD ID | ord-aec30557fa214165851007ec1a03f945 |
|---|
| 出典メモ | uspto-grants-1979_06 |
|---|
