Hydrochloric Acid → 2-Aminobenzene-1,4-diol hydrochloride

HRID 2368067ノート

反応式

HRID 2368067 の反応式
[N+:1]([C:4]1[CH:9]=[C:8]([OH:10])[CH:7]=[CH:6][C:5]=1[OH:11])([O-])=O.[ClH:12]>[C].[Pd]>[ClH:12].[NH2:1][C:4]1[CH:9]=[C:8]([OH:10])[CH:7]=[CH:6][C:5]=1[OH:11]

参加物

4

反応物 2

HCID 313Hydrochloric AcidHCID 43139181,4-Benzenediol, 2-nitro-

生成物 1

HCID 136850472-Aminobenzene-1,4-diol hydrochloride

試薬・触媒・溶媒 1

HCID 178418390HCID 178418390、化合物触媒

実験手順

A suspension of 2-nitrobenzene-1,4-diol (1.00 g) and 10% palladium carbon (containing water (50%), 1.00 g) in 1 M hydrochloric acid (13 mL) was stirred at room temperature for 5 hr under a hydrogen atmosphere. The reaction mixture was filtered, the filtrate was concentrated under reduced pressure, and the obtained solid was washed with ethyl acetate to give the title compound (949 mg).

後処理

  1. filtrationThe reaction mixture was filtered
  2. concentrationthe filtrate was concentrated under reduced pressure
  3. washthe obtained solid was washed with ethyl acetate

出典と根拠

ORDレコード
ord-6fca3bfb201147458a9d136b374616c1
出典データセット
uspto-grants-2014_04
特許番号
US08703758B2

反応ノート

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