Calcium Chloride → Calcium Stearate

HRID 236886ノート

反応式

HRID 236886 の反応式
[Cl-].[Ca+2:2].[Cl-].[C:4]([O-:23])(=[O:22])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21].[NH4+]>O>[C:4]([O-:23])(=[O:22])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21].[Ca+2:2].[C:4]([O-:23])(=[O:22])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]

参加物

4

反応物 2

HCID 5284359Calcium ChlorideHCID 9861187Ammonium Stearate

生成物 1

HCID 15324Calcium Stearate

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

272 ml. of water, 10 g. of Gelvatol 1-90 polyvinylalcohol and 5 g. of Acrysol WS-32 acrylic polymer were heated until the binders dissolved. 50 g. of stearic acid was then added and melted to form a liquid layer floating on the aqueous solution. 23 ml. of ammonium hyroxide (28% solution), which was the stoichiometric amount to form ammonium stearate, was then added dropwise to the gently stirred liquid. An intractable gel is formed which was transferred to a vigorously-stirred Waring Blendor, and then 20 g. of calcium chloride dissolved in 20 ml. of water slowly added until the mixture became solid. 50 ml. of water was then added with stirring until a creamy paste formed. After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power. The formation of ammonium stearate in situ is the preferred method of preparation because it allows a higher solids content to be obtained and yields smaller particles of calcium stearate. The density of the dry coating was 0.5 g./cc which is equivalent to about 50% void volume.

後処理

  1. additionwas then added dropwise to the gently stirred liquid
  2. customAn intractable gel is formed which
  3. customformed
  4. customAfter drying on a substrate this material
  5. customgave a pressure-sensitive film with excellent hiding power
  6. customthe preferred method of preparation because it
  7. customto be obtained

出典と根拠

ORDレコード
ord-a68358ed604a4a659cf5272e31886c4b
出典データセット
uspto-grants-1979_06
特許番号
US04158648

反応ノート

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