HCID 46947722、化合物 → HCID 46944761、化合物

HRID 2370588ノート

反応式

HRID 2370588 の反応式
[CH3:1][C:2]1([CH3:42])[N:6]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13]CCSCCCC(F)(F)C(F)(F)F)[C:5](=[O:27])[N:4]([C:28]2[CH:33]=[CH:32][C:31]([N+:34]([O-:36])=[O:35])=[C:30]([C:37]([F:40])([F:39])[F:38])[CH:29]=2)[C:3]1=[O:41].CS(OCCCCC[CH2:53][CH2:54][CH2:55][CH2:56][S:57][CH2:58][CH2:59][CH2:60][C:61]([F:67])([F:66])[C:62]([F:65])([F:64])[F:63])(=O)=O>>[CH3:1][C:2]1([CH3:42])[N:6]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:53][CH2:54][CH2:55][CH2:56][S:57][CH2:58][CH2:59][CH2:60][C:61]([F:67])([F:66])[C:62]([F:63])([F:65])[F:64])[C:5](=[O:27])[N:4]([C:28]2[CH:33]=[CH:32][C:31]([N+:34]([O-:36])=[O:35])=[C:30]([C:37]([F:39])([F:40])[F:38])[CH:29]=2)[C:3]1=[O:41]

参加物

3

反応物 2

HCID 46947722HCID 46947722、化合物HCID 58899364HCID 58899364、化合物

生成物 1

HCID 46944761HCID 46944761、化合物収率 43%

実験手順

The experimental protocol used is the same as that described for the synthesis of the compound of Example 1, 10-[(4,4,5,5,5-pentafluoropentypthio]undecyl methanesulphonate (prepared according to an experimental protocol similar to that described in WO 2005077968) replacing 9-[(4,4,5,5,5-pentafluoropentyl)-thio]nonyl methanesulphonate. The expected compound is obtained in the form of a pale yellow oil with a yield of 43% (328 mg).

後処理

  1. customprepared

出典と根拠

ORDレコード
ord-d599c1c39a2e4242a34edea6f01b846b
出典データセット
uspto-grants-2014_04
特許番号
US08710091B2

反応ノート

読み込み中…