N-Methylpiperidine → HCID 19907440、化合物
反応式
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]1[CH:13]=[CH:12][C:11]([CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]Br)=[CH:10][CH:9]=1.[CH3:21][N:22]1[CH2:27][CH2:26][CH2:25][CH2:24][CH2:23]1>C(O)C>[Br-:1].[Br-:1].[CH3:21][N+:22]1([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]2[CH:13]=[CH:12][C:11]([CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][N+:22]3([CH3:21])[CH2:27][CH2:26][CH2:25][CH2:24][CH2:23]3)=[CH:10][CH:9]=2)[CH2:27][CH2:26][CH2:25][CH2:24][CH2:23]1参加物
4
実験手順
First, 0.28 g of 1,4-bis(6-bromohexyl)benzene and 0.5 g of N-methylpiperidine were dissolved in 4 ml of absolute ethanol, and the mixture was refluxed for 2 hours and evaporated under a reduced pressure to remove the solvent. After adding acetone and then ethanol, the whole was allowed to stand in a freezer for 3 days. The resulting crystal was collected by filtration, washed with acetone and dried under a reduced pressure to obtain 0.125 g of the title compound as a colorless crystal.