化工社化工社 化学情報印刷レポート · 研究参考用
Mercuric cyanide → 4-trifluoromethylphenyl 2,3,4-tri-O-acetyl-1,5-dithio-beta-D-xylopyranoside
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Mercuric cyanide | HCID 11591 | — |
| 反応物 | 4-(Trifluoromethyl)thiophenol | HCID 136653 | — |
| 反応物 | 2,3,4-tri-O-acetyl-5-thio-alpha-xylopyranosyl bromide | HCID 10926314 | — |
| 生成物 | 4-trifluoromethylphenyl 2,3,4-tri-O-acetyl-1,5-dithio-beta-D-xylopyranoside | HCID 14795341 | 40% |
反応手順
If the procedure described in Preparation I is followed starting from 5.58 g (32.10-3 mol) of 4-trifluoromethylbenzenethiol, 8.87 g (35.10-3 mol) of mercuric cyanide, Hg(CN)2, and 12.3 g (35.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide, 6.2 g (yield: 40%) of the expected product are obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05101048 |
| 出典データセット | uspto-grants-1992_03 |
| ORD ID | ord-1da38ccf17f44fe1918c002c71af7f11 |
| 出典メモ | uspto-grants-1992_03 |